Hi,
I can't give any advice but would love to know how you get on! I've a Mastiff with an aftermarket exhaust, and I think it could run a bit better. Things are generally good but it could be smoother and I think I'm not getting all the power from the engine. I haven't touched the carb and honestly, I wouldn't know what to do with it!
Den and Duncmac have been playing with carbs. These threads might help
http://www.mzriders.com/viewtopic.php?f=20&t=5982
http://www.mzriders.com/viewtopic.php?f=3&t=7822&p=41227&hilit=carbs#p41227
They're good guys to contact too.
Good luck with it!