Hello buddy, glad to hear there's another Skorp on it's way to maturity!!!!
The best way forward, we have found, is exactly as David has stated, for the full "unleash the fury" tune you would find the bike an absolute terror to use on the road. 80+BHP on a single cylinder will piss the locals off with its bellowing exhaust note/rumble and the power/reliability would be a tad over the top for leisure use, although if your a power muncher and you have deep pockets then fair play.
Personally as Dave has also suggested, a 102mm bore on the barrel(standard is 100mm) and a Wiseco 102mm piston or a JE 102mm piston is then complemented with a Carrillo rod, this is vital, the bigger bore pushes the standard rod to it's limit and as Dave also stated, not having the whole job carried out all in one go will cost you for sure.BAD!
Next you will require a cam, as stated again by our budding enthusiast DT, and finally you will require the head Port & Polish work (Gas Flowed). This is a much more reliable way of unleashing enough power to really open up your engines potential without jeapordising it's durability and life. We carry out this work on a regular basis and find that this suits the "Street Tune" category. Having a twin pipe system made works really well on the XT660 engine and helps your bikes heart breathe more successfuly, like adding a bigger lung capacity! You can also add a set of CR Carbs, around £700 over here, that will also unleash the power. This mod can be added at a later date with a set of K&N filters and a little mod with your air-box housing. That reminds me we also add a Slipstream modified Dynojet kit.
We tune Eric Mersers racing Skorp, he races in the states and is about 60 years old, kick-ass. We have also carried out work for many other US Skorps that attend many meetings throughout the year.
Hope this helps...